Likewise, unavailable energy – entropy – can never decrease.Ī familiar demonstration of the second law is the flow of heat from hot things to cold, and never vice-versa. In a closed system, available energy can never increase. As long as entropy is defined as unavailable energy, this paraphrase of the second law is equivalent to the earlier ones above. Today, it is customary to use the term entropy to state the second law: Entropy in a closed system can never decrease. The American Heritage Dictionary gives as the first definition of entropy, "For a closed system, the quantitative measure of the amount of thermal energy not available to do work." So it's a negative kind of quantity, the opposite of available energy. Even the great physicist James Clerk Maxwell had it backward for a while (4). On another planet there could be physics without the concept of entropy. Historical accident has introduced this term to science. Surely not every conserved ratio corresponds to a real, physical quantity.
Clausius decided that the conserved ratio must correspond to a real, physical quantity, and he named it "entropy". The ratio was heat exchanged to absolute temperature. He had noticed that a certain ratio was constant in reversible, or ideal, heat cycles. The first opportunity for confusion arises when we introduce the term entropy into the mix. That would have been before the first law, conservation of energy, was discovered! In any case, modern scientists completely agree about the above principles. Feynman, however, says the French physicist Sadi Carnot discovered the second law 25 years earlier (3). The second law was formulated after nineteenth century engineers noticed that heat cannot pass from a colder body to a warmer body by itself.Īccording to philosopher of science Thomas Kuhn, the second law was first put into words by two scientists, Rudolph Clausius and William Thomson (Lord Kelvin), using different examples, in 1850-51 (2). This means that a perpetual motion machine is impossible. The second law is a straightforward law of physics with the consequence that, in a closed system, you can't finish any real physical process with as much useful energy as you had to start with - some is always wasted. So why do people say that life violates the second law of thermodynamics? What is the second law of thermodynamics? This is not the case we know of nothing in the universe that violates that law. Sometimes people say that life violates the second law of thermodynamics. The use of thermodynamics in biology has a long history rich in confusion.
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